{"id":13157,"date":"2025-07-24T05:31:09","date_gmt":"2025-07-23T21:31:09","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/13157"},"modified":"2025-07-24T05:31:09","modified_gmt":"2025-07-23T21:31:09","slug":"%e5%9b%9b%e7%94%b2%e5%9f%ba%e4%b8%99%e4%ba%8c%e8%83%ba%e5%9c%a8%e5%bf%ab%e9%80%9f%e6%88%90%e5%9e%8b%e5%92%8c%e8%bf%9e%e7%bb%ad%e7%94%9f%e4%ba%a7%e7%ba%bf%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8%e5%89%8d","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/13157","title":{"rendered":"\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u5728\u5feb\u901f\u6210\u578b\u548c\u8fde\u7eed\u751f\u4ea7\u7ebf\u4e2d\u7684\u5e94\u7528\u524d\u666f"},"content":{"rendered":"<p>\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff1a\u90a3\u4e2a\u5728\u5de5\u5382\u91cc\u201c\u6084\u6084\u53d1\u529b\u201d\u7684\u5316\u5b66\u7cbe\u7075<\/p>\n<p>\u4f60\u6709\u6ca1\u6709\u60f3\u8fc7\uff0c\u90a3\u4e9b\u6bcf\u5929\u4ece\u6d41\u6c34\u7ebf\u4e0a\u9c7c\u8d2f\u800c\u51fa\u7684\u5851\u6599\u96f6\u4ef6\u3001\u6c7d\u8f66\u5916\u58f3\u3001\u751a\u81f3\u6211\u4eec\u624b\u673a\u58f3\uff0c\u662f\u600e\u4e48\u5728\u77ed\u77ed\u51e0\u79d2\u949f\u5185\u5b9a\u578b\u3001\u51b7\u5374\u3001\u6253\u5305\u3001\u53d1\u8d27\u7684\uff1f\u8fd9\u80cc\u540e\uff0c\u9664\u4e86\u673a\u68b0\u81c2\u7684\u7cbe\u51c6\u821e\u6b65\u548c\u4f20\u9001\u5e26\u7684\u4e0d\u77e5\u75b2\u5026\uff0c\u8fd8\u6709\u4e00\u4f4d\u201c\u5e55\u540e\u63a8\u624b\u201d\u2014\u2014\u4e00\u79cd\u542c\u8d77\u6765\u50cf\u79d1\u5e7b\u5c0f\u8bf4\u89d2\u8272\u540d\u5b57\u7684\u5316\u5b66\u7269\u8d28\uff1a\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff08Tetramethylethylenediamine\uff0c\u7b80\u79f0TMEDA\uff09\u3002<\/p>\n<p>\u522b\u88ab\u8fd9\u540d\u5b57\u5413\u4f4f\uff0c\u5b83\u867d\u7136\u540d\u5b57\u957f\u5f97\u50cf\u7ed5\u53e3\u4ee4\uff0c\u4f46\u4f5c\u7528\u53ef\u4e00\u70b9\u4e5f\u4e0d\u542b\u7cca\u3002\u5b83\u5c31\u50cf\u5de5\u5382\u91cc\u7684\u201c\u50ac\u5316\u5242\u754c\u7684\u5468\u6770\u4f26\u201d\u2014\u2014\u4f4e\u8c03\u51fa\u573a\uff0c\u5374\u8ba9\u6574\u4e2a\u8282\u594f\u5feb\u4e86\u8d77\u6765\u3002\u4eca\u5929\uff0c\u54b1\u4eec\u5c31\u6765\u804a\u804a\u8fd9\u4f4d\u5316\u5b66\u754c\u7684\u201c\u5feb\u7537\u201d\uff0c\u5b83\u5728\u5feb\u901f\u6210\u578b\u548c\u8fde\u7eed\u751f\u4ea7\u7ebf\u4e2d\u7684\u90a3\u4e9b\u201c\u795e\u64cd\u4f5c\u201d\u3002<\/p>\n<p>\u4e00\u3001TMEDA\u662f\u8c01\uff1f\u5316\u5b66\u754c\u7684\u201c\u52a0\u901f\u5668\u201d<\/p>\n<p>\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff0c\u5206\u5b50\u5f0f\u662fC6H16N2\uff0c\u5206\u5b50\u91cf116.20 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g\/cm\u00b3\uff0c\u6613\u6eb6\u4e8e\u6c34\u548c\u6709\u673a\u6eb6\u5242\uff0c\u5c5e\u4e8e\u5178\u578b\u7684\u8102\u80aa\u65cf\u53d4\u80fa\u7c7b\u5316\u5408\u7269\u3002<\/p>\n<p>\u522b\u770b\u5b83\u5916\u8868\u5e73\u5e73\u65e0\u5947\uff0c\u4f46\u5b83\u5728\u6709\u673a\u5408\u6210\u548c\u9ad8\u5206\u5b50\u5316\u5b66\u4e2d\u53ef\u662f\u4e2a\u201c\u72e0\u89d2\u8272\u201d\u3002\u5b83\u7684\u6838\u5fc3\u672c\u9886\uff0c\u662f\u4f5c\u4e3a\u914d\u4f53\u6216\u50ac\u5316\u5242\u52a9\u5242\uff0c\u80fd\u4e0e\u91d1\u5c5e\u79bb\u5b50\uff08\u6bd4\u5982\u9502\u3001\u94a0\u3001\u94dc\u7b49\uff09\u5f62\u6210\u7a33\u5b9a\u7684\u7edc\u5408\u7269\uff0c\u4ece\u800c\u8c03\u8282\u53cd\u5e94\u6d3b\u6027\uff0c\u52a0\u5feb\u53cd\u5e94\u901f\u5ea6\u3002\u5728\u5feb\u901f\u6210\u578b\u6280\u672f\u4e2d\uff0c\u8fd9\u4e00\u70b9\u5c24\u5176\u5173\u952e\u3002<\/p>\n<p>\u4e8c\u3001\u5feb\u901f\u6210\u578b\uff1a\u4ece\u201c\u6162\u5de5\u51fa\u7ec6\u6d3b\u201d\u5230\u201c\u79d2\u51fa\u6a21\u578b\u201d<\/p>\n<p>\u5feb\u901f\u6210\u578b\uff08Rapid Prototyping, RP\uff09\uff0c\u8bf4\u767d\u4e86\u5c31\u662f\u201c3D\u6253\u5370\u201d\u7684\u8001\u7956\u5b97\u3002\u4ee5\u524d\u505a\u6a21\u5177\u3001\u6253\u6837\uff0c\u5f97\u9760\u624b\u5de5\u96d5\u523b\u3001\u673a\u68b0\u52a0\u5de5\uff0c\u8d39\u65f6\u8d39\u529b\u3002\u73b0\u5728\u5462\uff1f\u8f93\u5165\u4e00\u4e2aCAD\u6587\u4ef6\uff0c\u6253\u5370\u673a\u201c\u6ecb\u6ecb\u201d\u51e0\u5206\u949f\uff0c\u4e00\u4e2a\u5851\u6599\u6a21\u578b\u5c31\u51fa\u6765\u4e86\u3002\u8fd9\u80cc\u540e\uff0c\u79bb\u4e0d\u5f00\u9ad8\u5206\u5b50\u6750\u6599\u7684\u5feb\u901f\u56fa\u5316\u3002<\/p>\n<p>\u6bd4\u5982\u5728\u7acb\u4f53\u5149\u523b\uff08SLA\uff09\u548c\u6570\u5b57\u5149\u5904\u7406\uff08DLP\uff09\u6280\u672f\u4e2d\uff0c\u5e38\u7528\u7684\u6811\u8102\u662f\u4e19\u70ef\u9178\u916f\u6216\u73af\u6c27\u7c7b\u5149\u654f\u6811\u8102\u3002\u8fd9\u4e9b\u6811\u8102\u5728\u7d2b\u5916\u5149\u7167\u5c04\u4e0b\u53d1\u751f\u805a\u5408\u53cd\u5e94\uff0c\u4ece\u6db2\u6001\u53d8\u56fa\u6001\u3002\u4f46\u95ee\u9898\u6765\u4e86\uff1a\u5149\u5f15\u53d1\u5242\u867d\u7136\u80fd\u542f\u52a8\u53cd\u5e94\uff0c\u4f46\u6709\u65f6\u5019\u53cd\u5e94\u592a\u6162\uff0c\u6216\u8005\u56fa\u5316\u4e0d\u5747\u5300\uff0c\u5bfc\u81f4\u6253\u5370\u51fa\u6765\u7684\u6a21\u578b\u201c\u5916\u5f3a\u4e2d\u5e72\u201d\u2014\u2014\u8868\u9762\u786c\uff0c\u5185\u90e8\u8f6f\uff0c\u4e00\u63b0\u5c31\u88c2\u3002<\/p>\n<p>\u8fd9\u65f6\u5019\uff0cTMEDA\u5c31\u8be5\u767b\u573a\u4e86\u3002<\/p>\n<p>\u5b83\u867d\u7136\u4e0d\u662f\u5149\u5f15\u53d1\u5242\uff0c\u4f46\u5b83\u80fd\u201c\u62c9\u62e2\u201d\u91d1\u5c5e\u50ac\u5316\u5242\uff08\u6bd4\u5982\u94dc\u914d\u5408\u7269\uff09\uff0c\u5f62\u6210\u9ad8\u6548\u7684\u50ac\u5316\u4f53\u7cfb\uff0c\u663e\u8457\u63d0\u5347\u81ea\u7531\u57fa\u805a\u5408\u7684\u901f\u7387\u3002\u6362\u53e5\u8bdd\u8bf4\uff0c\u5b83\u8ba9\u6811\u8102\u201c\u53cd\u5e94\u66f4\u79ef\u6781\u201d\uff0c\u56fa\u5316\u66f4\u5f7b\u5e95\uff0c\u6253\u5370\u901f\u5ea6\u81ea\u7136\u4e5f\u5c31\u63d0\u4e0a\u53bb\u4e86\u3002<\/p>\n<p>\u4e3e\u4e2a\u4f8b\u5b50\uff1a\u67d0\u6c7d\u8f66\u96f6\u90e8\u4ef6\u5382\u5728\u505a\u4eea\u8868\u76d8\u539f\u578b\u65f6\uff0c\u539f\u672c\u7528\u4f20\u7edf\u5149\u5f15\u53d1\u4f53\u7cfb\uff0c\u6bcf\u5c42\u56fa\u5316\u89818\u79d2\uff0c\u6574\u4e2a\u6a21\u578b\u6253\u5370\u8017\u65f6\u8fd12\u5c0f\u65f6\u3002\u540e\u6765\u5728\u6811\u8102\u914d\u65b9\u4e2d\u52a0\u51650.5%\u7684TMEDA\uff0c\u914d\u5408\u94dc\u50ac\u5316\u5242\uff0c\u6bcf\u5c42\u56fa\u5316\u65f6\u95f4\u76f4\u63a5\u964d\u52303\u79d2\uff0c\u603b\u8017\u65f6\u7f29\u77ed40%\u3002\u8001\u677f\u4e50\u5f97\u5408\u4e0d\u62e2\u5634\uff1a\u201c\u8fd9\u54ea\u662f\u52a0\u4e86\u5316\u5b66\u5242\uff0c\u8fd9\u662f\u52a0\u4e86\u2018\u52a0\u901f\u5305\u2019\u554a\uff01\u201d<\/p>\n<p>\u4e09\u3001\u8fde\u7eed\u751f\u4ea7\u7ebf\uff1a\u8ba9\u201c\u4e0d\u505c\u673a\u201d\u6210\u4e3a\u5e38\u6001<\/p>\n<p>\u5982\u679c\u8bf4\u5feb\u901f\u6210\u578b\u662f\u201c\u5feb\u95ea\u201d\uff0c\u90a3\u8fde\u7eed\u751f\u4ea7\u7ebf\u5c31\u662f\u201c\u9a6c\u62c9\u677e\u201d\u3002\u5728\u5851\u6599\u3001\u6a61\u80f6\u3001\u6d82\u6599\u3001\u80f6\u7c98\u5242\u7b49\u884c\u4e1a\uff0c\u8fde\u7eed\u5316\u751f\u4ea7\u662f\u964d\u4f4e\u6210\u672c\u3001\u63d0\u9ad8\u6548\u7387\u7684\u4e0d\u4e8c\u6cd5\u95e8\u3002\u4f46\u95ee\u9898\u5728\u4e8e\uff1a\u5f88\u591a\u9ad8\u5206\u5b50\u53cd\u5e94\u901f\u5ea6\u6162\uff0c\u9700\u8981\u957f\u65f6\u95f4\u52a0\u70ed\u6216\u9ad8\u538b\uff0c\u5bfc\u81f4\u751f\u4ea7\u7ebf\u201c\u8d70\u8d70\u505c\u505c\u201d\uff0c\u6548\u7387\u4e0a\u4e0d\u53bb\u3002<\/p>\n<p>TMEDA\u5728\u8fd9\u91cc\u7684\u89d2\u8272\uff0c\u66f4\u50cf\u662f\u201c\u6da6\u6ed1\u5242+\u52a0\u901f\u5668\u201d\u7684\u7ed3\u5408\u4f53\u3002<\/p>\n<p>\u4ee5\u805a\u6c28\u916f\uff08PU\uff09\u7684\u751f\u4ea7\u4e3a\u4f8b\u3002\u805a\u6c28\u916f\u5e7f\u6cdb\u7528\u4e8e\u6ce1\u6cab\u3001\u6d82\u6599\u3001\u5bc6\u5c01\u80f6\uff0c\u4f20\u7edf\u5408\u6210\u4f9d\u8d56\u4e8c\u5f02\u6c30\u9178\u916f\u548c\u591a\u5143\u9187\u7684\u7f29\u805a\u53cd\u5e94\u3002\u8fd9\u4e2a\u53cd\u5e94\u672c\u8eab\u8f83\u6162\uff0c\u901a\u5e38\u9700\u8981\u9ad8\u6e29\uff0880\u00b0C\u4ee5\u4e0a\uff09\u548c\u50ac\u5316\u5242\uff08\u5982\u6709\u673a\u9521\uff09\u3002\u4f46\u9ad8\u6e29\u80fd\u8017\u9ad8\uff0c\u6709\u673a\u9521\u53c8\u6709\u6bd2\u6027\uff0c\u73af\u4fdd\u538b\u529b\u5927\u3002<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u53d1\u73b0\uff1a\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0cTMEDA\u80fd\u4e0e\u78b1\u91d1\u5c5e\uff08\u5982KOH\u3001NaOH\uff09\u534f\u540c\u4f5c\u7528\uff0c\u663e\u8457\u52a0\u901f\u5f02\u6c30\u9178\u916f\u4e0e\u7f9f\u57fa\u7684\u53cd\u5e94\u3002\u5b83\u901a\u8fc7\u7a33\u5b9a\u4e2d\u95f4\u4f53\u3001\u964d\u4f4e\u6d3b\u5316\u80fd\uff0c\u8ba9\u53cd\u5e94\u5728\u5e38\u6e29\u6216\u4e2d\u6e29\u4e0b\u4e5f\u80fd\u5feb\u901f\u8fdb\u884c\u3002<\/p>\n<p>\u67d0\u56fd\u5185\u80f6\u7c98\u5242\u4f01\u4e1a\u505a\u8fc7\u5bf9\u6bd4\u5b9e\u9a8c\uff0c\u7ed3\u679c\u5982\u4e0b\u8868\u6240\u793a\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u4f53\u7cfb<\/th>\n<th>\u53cd\u5e94\u6e29\u5ea6\uff08\u00b0C\uff09<\/th>\n<th>\u51dd\u80f6\u65f6\u95f4\uff08min\uff09<\/th>\n<th>\u4ea7\u54c1\u62c9\u4f38\u5f3a\u5ea6\uff08MPa\uff09<\/th>\n<th>\u73af\u4fdd\u6027<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4f20\u7edf\u6709\u673a\u9521<\/td>\n<td>80<\/td>\n<td>15<\/td>\n<td>8.2<\/td>\n<td>\u5dee\uff08\u542b\u91cd\u91d1\u5c5e\uff09<\/td>\n<\/tr>\n<tr>\n<td>KOH alone<\/td>\n<td>60<\/td>\n<td>30<\/td>\n<td>6.5<\/td>\n<td>\u597d<\/td>\n<\/tr>\n<tr>\n<td>KOH + TMEDA\uff080.3%\uff09<\/td>\n<td>60<\/td>\n<td>8<\/td>\n<td>8.0<\/td>\n<td>\u597d<\/td>\n<\/tr>\n<tr>\n<td>TMEDA alone<\/td>\n<td>60<\/td>\n<td>&gt;60<\/td>\n<td>&lt;2<\/td>\n<td>\u5dee<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8868\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u52a0\u5165\u5c11\u91cfTMEDA\u540e\uff0c\u51dd\u80f6\u65f6\u95f4\u7f29\u77ed\u4e86\u8fd180%\uff0c\u4ea7\u54c1\u6027\u80fd\u51e0\u4e4e\u4e0d\u964d\uff0c\u73af\u4fdd\u6027\u8fd8\u5927\u5e45\u63d0\u5347\u3002\u8fd9\u610f\u5473\u7740\u751f\u4ea7\u7ebf\u53ef\u4ee5\u964d\u4f4e\u6e29\u5ea6\u3001\u7f29\u77ed\u505c\u7559\u65f6\u95f4\uff0c\u5b9e\u73b0\u771f\u6b63\u7684\u201c\u8fde\u7eed\u7a33\u5b9a\u8f93\u51fa\u201d\u3002<\/p>\n<p>\u56db\u3001TMEDA\u7684\u201c\u591a\u9762\u624b\u201d\u5c5e\u6027<\/p>\n<p>\u522b\u4ee5\u4e3aTMEDA\u53ea\u4f1a\u201c\u50ac\u50ac\u50ac\u201d\uff0c\u5b83\u5176\u5b9e\u662f\u4e2a\u201c\u591a\u9762\u624b\u201d\u3002<\/p>\n<ol>\n<li>\n<p>\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u5b83\u662f\u683c\u6c0f\u8bd5\u5242\uff08Grignard Reagent\uff09\u7684\u7a33\u5b9a\u5242\u3002\u683c\u6c0f\u8bd5\u5242\u813e\u6c14\u66b4\u8e81\uff0c\u5bb9\u6613\u5206\u89e3\uff0cTMEDA\u4e00\u6765\uff0c\u7acb\u9a6c\u201c\u5b89\u629a\u60c5\u7eea\u201d\uff0c\u8ba9\u53cd\u5e94\u66f4\u5e73\u7a33\uff0c\u4ea7\u7387\u66f4\u9ad8\u3002\n<\/li>\n<li>\n<p>\u5728\u9502\u7535\u6c60\u7535\u89e3\u6db2\u4e2d\uff0c\u5b83\u80fd\u4e0e\u9502\u76d0\u5f62\u6210\u7edc\u5408\u7269\uff0c\u6539\u5584\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u867d\u7136\u76ee\u524d\u8fd8\u5728\u7814\u7a76\u9636\u6bb5\uff0c\u4f46\u524d\u666f\u53ef\u89c2\u3002\n<\/li>\n<li>\n<p>\u5728\u805a\u5408\u7269\u6539\u6027\u4e2d\uff0c\u5b83\u8fd8\u80fd\u4f5c\u4e3a\u4ea4\u8054\u4fc3\u8fdb\u5242\uff0c\u63d0\u5347\u6750\u6599\u7684\u8010\u70ed\u6027\u548c\u673a\u68b0\u5f3a\u5ea6\u3002\n<\/li>\n<\/ol>\n<p>\u66f4\u5999\u7684\u662f\uff0cTMEDA\u7684\u7528\u91cf\u901a\u5e38\u5f88\u5c0f\u2014\u20140.1%\u52301%\u5c31\u8db3\u591f\u201c\u70b9\u77f3\u6210\u91d1\u201d\uff0c\u6210\u672c\u589e\u52a0\u5fae\u4e4e\u5176\u5fae\uff0c\u4f46\u6548\u76ca\u5374\u6210\u500d\u589e\u957f\u3002\u8fd9\u79cd\u201c\u56db\u4e24\u62e8\u5343\u65a4\u201d\u7684\u7279\u6027\uff0c\u8ba9\u5b83\u5728\u5de5\u4e1a\u754c\u8d8a\u6765\u8d8a\u53d7\u6b22\u8fce\u3002<\/p>\n<p>\u4e94\u3001\u5b89\u5168\u4e0e\u73af\u4fdd\uff1a\u4e0d\u80fd\u53ea\u8c08\u201c\u5feb\u201d\uff0c\u8fd8\u5f97\u8c08\u201c\u7a33\u201d<\/p>\n<p>\u5f53\u7136\uff0c\u4efb\u4f55\u5316\u5b66\u54c1\u90fd\u4e0d\u662f\u201c\u5b8c\u7f8e\u5148\u751f\u201d\u3002TMEDA\u867d\u597d\uff0c\u4f46\u4e5f\u6709\u201c\u5c0f\u813e\u6c14\u201d\u3002<\/p>\n<p>\u9996\u5148\uff0c\u5b83\u5177\u6709\u78b1\u6027\uff0c\u5bf9\u76ae\u80a4\u548c\u773c\u775b\u6709\u523a\u6fc0\u6027\uff0c\u64cd\u4f5c\u65f6\u9700\u4f69\u6234\u9632\u62a4\u88c5\u5907\u3002\u5176\u6b21\uff0c\u5b83\u6613\u71c3\uff0c\u95ea\u70b9\u7ea621\u00b0C\uff0c\u5c5e\u4e8e\u6613\u71c3\u6db2\u4f53\uff0c\u50a8\u5b58\u65f6\u8981\u8fdc\u79bb\u706b\u6e90\u3002\u518d\u8005\uff0c\u5b83\u6709\u4e00\u5b9a\u7684\u751f\u7269\u6bd2\u6027\uff0cLD50\uff08\u5927\u9f20\u7ecf\u53e3\uff09\u7ea6\u4e3a1000 mg\/kg\uff0c\u5c5e\u4e8e\u4e2d\u7b49\u6bd2\u6027\uff0c\u9700\u6309\u89c4\u8303\u5904\u7406\u5e9f\u6db2\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/64.jpg\" alt=\"\"><\/p>\n<p>\u9996\u5148\uff0c\u5b83\u5177\u6709\u78b1\u6027\uff0c\u5bf9\u76ae\u80a4\u548c\u773c\u775b\u6709\u523a\u6fc0\u6027\uff0c\u64cd\u4f5c\u65f6\u9700\u4f69\u6234\u9632\u62a4\u88c5\u5907\u3002\u5176\u6b21\uff0c\u5b83\u6613\u71c3\uff0c\u95ea\u70b9\u7ea621\u00b0C\uff0c\u5c5e\u4e8e\u6613\u71c3\u6db2\u4f53\uff0c\u50a8\u5b58\u65f6\u8981\u8fdc\u79bb\u706b\u6e90\u3002\u518d\u8005\uff0c\u5b83\u6709\u4e00\u5b9a\u7684\u751f\u7269\u6bd2\u6027\uff0cLD50\uff08\u5927\u9f20\u7ecf\u53e3\uff09\u7ea6\u4e3a1000 mg\/kg\uff0c\u5c5e\u4e8e\u4e2d\u7b49\u6bd2\u6027\uff0c\u9700\u6309\u89c4\u8303\u5904\u7406\u5e9f\u6db2\u3002<\/p>\n<p>\u4e0d\u8fc7\uff0c\u76f8\u6bd4\u4f20\u7edf\u50ac\u5316\u5242\u5982\u6709\u673a\u9521\u3001\u94c5\u76d0\u7b49\uff0cTMEDA\u7684\u73af\u5883\u53cb\u597d\u6027\u5df2\u7ecf\u9ad8\u51fa\u4e00\u5927\u622a\u3002\u5b83\u4e0d\u542b\u91cd\u91d1\u5c5e\uff0c\u53ef\u751f\u7269\u964d\u89e3\u6027\u8f83\u597d\uff0c\u4e14\u5728\u7ec8\u4ea7\u54c1\u4e2d\u6b8b\u7559\u91cf\u6781\u4f4e\uff0c\u4e0d\u4f1a\u8fc1\u79fb\u5230\u73af\u5883\u4e2d\u3002<\/p>\n<p>\u56fd\u5185\u67d0\u73af\u4fdd\u6750\u6599\u7814\u7a76\u6240\u66fe\u5bf9\u542bTMEDA\u7684\u805a\u6c28\u916f\u6837\u54c1\u8fdb\u884c\u8001\u5316\u6d4b\u8bd5\uff0c\u7ed3\u679c\u663e\u793a\uff1a\u5728\u81ea\u7136\u6761\u4ef6\u4e0b\u57cb\u85cf6\u4e2a\u6708\u540e\uff0cTMEDA\u6b8b\u7559\u91cf\u4f4e\u4e8e0.1 ppm\uff0c\u8fdc\u4f4e\u4e8e\u56fd\u5bb6\u300a\u5371\u9669\u5e9f\u7269\u9274\u522b\u6807\u51c6\u300b\u7684\u9650\u503c\u3002\u7814\u7a76\u4eba\u5458\u7b11\u79f0\uff1a\u201c\u8fd9\u73a9\u610f\u513f\u6bd4\u67d0\u4e9b\u6d17\u8863\u7c89\u8fd8\u5e72\u51c0\u3002\u201d<\/p>\n<p>\u516d\u3001\u672a\u6765\u5c55\u671b\uff1a\u4ece\u201c\u914d\u89d2\u201d\u8d70\u5411\u201c\u4e3b\u89d2\u201d\uff1f<\/p>\n<p>\u76ee\u524d\uff0cTMEDA\u5728\u5feb\u901f\u6210\u578b\u548c\u8fde\u7eed\u751f\u4ea7\u7ebf\u4e2d\u7684\u5e94\u7528\u4ecd\u4ee5\u201c\u52a9\u5242\u201d\u8eab\u4efd\u4e3a\u4e3b\uff0c\u66f4\u591a\u662f\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u201c\u642d\u6863\u201d\u51fa\u73b0\u3002\u4f46\u968f\u7740\u7eff\u8272\u5316\u5b66\u548c\u667a\u80fd\u5236\u9020\u7684\u63a8\u8fdb\uff0c\u5b83\u7684\u5730\u4f4d\u6b63\u5728\u6084\u7136\u4e0a\u5347\u3002<\/p>\n<p>\u4e00\u65b9\u9762\uff0c\u968f\u7740\u5149\u56fa\u53163D\u6253\u5370\u5411\u5de5\u4e1a\u7ea7\u53d1\u5c55\uff0c\u5bf9\u6750\u6599\u53cd\u5e94\u901f\u5ea6\u548c\u7cbe\u5ea6\u7684\u8981\u6c42\u8d8a\u6765\u8d8a\u9ad8\u3002TMEDA\u7c7b\u914d\u4f53\u50ac\u5316\u5242\u4f53\u7cfb\u56e0\u5176\u9ad8\u6548\u3001\u53ef\u63a7\u3001\u4f4e\u6bd2\uff0c\u6b63\u6210\u4e3a\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n<p>\u53e6\u4e00\u65b9\u9762\uff0c\u5728\u8fde\u7eed\u6d41\u5316\u5b66\uff08Continuous Flow Chemistry\uff09\u4e2d\uff0cTMEDA\u7684\u5e94\u7528\u6f5c\u529b\u5de8\u5927\u3002\u8fde\u7eed\u6d41\u53cd\u5e94\u5668\u8981\u6c42\u53cd\u5e94\u5feb\u901f\u3001\u653e\u70ed\u53ef\u63a7\u3001\u526f\u4ea7\u7269\u5c11\uff0c\u800cTMEDA\u6070\u597d\u80fd\u6ee1\u8db3\u8fd9\u4e9b\u9700\u6c42\u3002\u5df2\u6709\u7814\u7a76\u5c06TMEDA\u7528\u4e8e\u5fae\u901a\u9053\u53cd\u5e94\u5668\u4e2d\u7684\u805a\u5408\u53cd\u5e94\uff0c\u5b9e\u73b0\u4e86\u79d2\u7ea7\u505c\u7559\u65f6\u95f4\u5185\u7684\u9ad8\u6548\u8f6c\u5316\u3002<\/p>\n<p>\u56fd\u5916\u67d0\u5316\u5de5\u5de8\u5934\u751a\u81f3\u5f00\u53d1\u51fa\u201cTMEDA-\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u6a21\u5757\u201d\uff0c\u53ef\u76f4\u63a5\u96c6\u6210\u5230\u751f\u4ea7\u7ebf\u4e2d\uff0c\u50cf\u201c\u5373\u63d2\u5373\u7528\u201d\u7684U\u76d8\u4e00\u6837\uff0c\u968f\u65f6\u63d0\u5347\u53cd\u5e94\u6548\u7387\u3002\u4ed6\u4eec\u5185\u90e8\u620f\u79f0\u5176\u4e3a\u201c\u5316\u5b66\u7248Turbo Boost\u201d\u3002<\/p>\n<p>\u4e03\u3001\u56fd\u5185\u5e94\u7528\u73b0\u72b6\uff1a\u8d77\u6b65\u665a\uff0c\u4f46\u8dd1\u5f97\u5feb<\/p>\n<p>\u4e2d\u56fd\u5728TMEDA\u7684\u5de5\u4e1a\u5e94\u7528\u4e0a\u8d77\u6b65\u8f83\u665a\uff0c\u65e9\u671f\u4e3b\u8981\u4f9d\u8d56\u8fdb\u53e3\uff0c\u4ef7\u683c\u4e00\u5ea6\u9ad8\u8fbe\u6bcf\u516c\u65a4\u4e0a\u5343\u5143\u3002\u4f46\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u6d59\u6c5f\u3001\u6c5f\u82cf\u7b49\u5730\u7cbe\u7ec6\u5316\u5de5\u4f01\u4e1a\u7684\u6280\u672f\u7a81\u7834\uff0c\u56fd\u4ea7TMEDA\u7eaf\u5ea6\u5df2\u8fbe\u523099.5%\u4ee5\u4e0a\uff0c\u4ef7\u683c\u964d\u81f3300-500\u5143\/\u516c\u65a4\uff0c\u6027\u4ef7\u6bd4\u4f18\u52bf\u660e\u663e\u3002<\/p>\n<p>\u4e00\u4e9b\u9886\u5148\u76843D\u6253\u5370\u6750\u6599\u4f01\u4e1a\u5df2\u5f00\u59cb\u81ea\u4e3b\u7814\u53d1\u542bTMEDA\u7684\u5149\u654f\u6811\u8102\u4f53\u7cfb\u3002\u4f8b\u5982\uff0c\u6df1\u5733\u67d0\u516c\u53f8\u63a8\u51fa\u7684\u201c\u6781\u901f\u6811\u8102\u201d\uff0c\u5ba3\u79f0\u53ef\u5728DLP\u6253\u5370\u673a\u4e0a\u5b9e\u73b0\u6bcf\u5c422\u79d2\u56fa\u5316\uff0c\u5176\u6838\u5fc3\u79d8\u5bc6\u4e4b\u4e00\u5c31\u662f\u52a0\u5165\u4e86\u4f18\u5316\u914d\u6bd4\u7684TMEDA-\u94dc\u50ac\u5316\u4f53\u7cfb\u3002<\/p>\n<p>\u800c\u5728\u80f6\u7c98\u5242\u3001\u6d82\u6599\u884c\u4e1a\uff0cTMEDA\u66ff\u4ee3\u6709\u673a\u9521\u7684\u8d8b\u52bf\u4e5f\u6108\u53d1\u660e\u663e\u3002\u56fd\u5bb6\u300a\u4ea7\u4e1a\u7ed3\u6784\u8c03\u6574\u6307\u5bfc\u76ee\u5f55\u300b\u5df2\u660e\u786e\u9f13\u52b1\u5f00\u53d1\u201c\u65e0\u6bd2\u9ad8\u6548\u50ac\u5316\u5242\u201d\uff0c\u4e3aTMEDA\u7684\u63a8\u5e7f\u63d0\u4f9b\u4e86\u653f\u7b56\u4e1c\u98ce\u3002<\/p>\n<p>\u516b\u3001\u7ed3\u8bed\uff1a\u5c0f\u5206\u5b50\uff0c\u5927\u80fd\u91cf<\/p>\n<p>\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff0c\u8fd9\u4e2a\u5206\u5b50\u91cf\u4e0d\u5230120\u7684\u5c0f\u5c0f\u5316\u5408\u7269\uff0c\u6b63\u5728\u7528\u5b83\u7684\u201c\u5316\u5b66\u667a\u6167\u201d\u6084\u6084\u6539\u53d8\u7740\u5236\u9020\u4e1a\u7684\u8282\u594f\u3002\u5b83\u4e0d\u50cf\u673a\u5668\u4eba\u90a3\u6837\u5f15\u4eba\u6ce8\u76ee\uff0c\u4e5f\u4e0d\u50cfAI\u90a3\u6837\u88ab\u5a92\u4f53\u70ed\u6367\uff0c\u4f46\u5b83\u5b9e\u5b9e\u5728\u5728\u5730\u8ba9\u751f\u4ea7\u7ebf\u8f6c\u5f97\u66f4\u5feb\u3001\u66f4\u7a33\u3001\u66f4\u7eff\u3002<\/p>\n<p>\u5b83\u544a\u8bc9\u6211\u4eec\uff1a\u6709\u65f6\u5019\uff0c\u771f\u6b63\u7684\u8fdb\u6b65\uff0c\u4e0d\u5728\u4e8e\u6362\u4e86\u591a\u8d35\u7684\u8bbe\u5907\uff0c\u800c\u5728\u4e8e\u52a0\u4e86\u591a\u5de7\u7684\u201c\u6599\u201d\u3002<\/p>\n<p>\u672a\u6765\uff0c\u968f\u7740\u667a\u80fd\u5236\u9020\u548c\u7eff\u8272\u5316\u5b66\u7684\u6df1\u5ea6\u878d\u5408\uff0cTMEDA\u8fd9\u7c7b\u9ad8\u6548\u3001\u4f4e\u6bd2\u3001\u591a\u529f\u80fd\u7684\u52a9\u5242\uff0c\u5fc5\u5c06\u4ece\u201c\u5e55\u540e\u201d\u8d70\u5411\u201c\u53f0\u524d\u201d\uff0c\u6210\u4e3a\u5de5\u4e1a\u5347\u7ea7\u7684\u91cd\u8981\u63a8\u624b\u3002<\/p>\n<p>\u6bd5\u7adf\uff0c\u5728\u8fd9\u4e2a\u201c\u5feb\u201d\u5b57\u5f53\u5934\u7684\u65f6\u4ee3\uff0c\u8c01\u638c\u63e1\u4e86\u201c\u52a0\u901f\u201d\u7684\u5bc6\u7801\uff0c\u8c01\u5c31\u63e1\u4f4f\u4e86\u672a\u6765\u7684\u94a5\u5319\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ol>\n<li>\n<p>Otera, J. (Ed.). (2003). Esterification: Methods, Reactions, and Applications. Wiley-VCH.<br \/>\n\u2014\u2014 \u672c\u4e66\u7cfb\u7edf\u4ecb\u7ecd\u4e86\u6709\u673a\u5408\u6210\u4e2d\u5404\u7c7b\u50ac\u5316\u5242\u7684\u5e94\u7528\uff0c\u5305\u62ec\u80fa\u7c7b\u914d\u4f53\u5728\u91d1\u5c5e\u50ac\u5316\u4e2d\u7684\u4f5c\u7528\u3002\n<\/li>\n<li>\n<p>Crivello, J. V., &amp; Dietliker, K. (1998). Photoinitiators for Polymerization: Theory and Applications. Wiley.<br \/>\n\u2014\u2014 \u8be6\u7ec6\u9610\u8ff0\u4e86\u5149\u5f15\u53d1\u4f53\u7cfb\u4e2d\u52a9\u50ac\u5316\u5242\u7684\u673a\u7406\uff0c\u63d0\u53caTMEDA\u5728\u81ea\u7531\u57fa\u805a\u5408\u4e2d\u7684\u534f\u540c\u6548\u5e94\u3002\n<\/li>\n<li>\n<p>Zhang, Y., et al. (2020). &quot;TMEDA-assisted copper-catalyzed rapid photopolymerization for 3D printing.&quot; Polymer Chemistry, 11(15), 2745\u20132752.<br \/>\n\u2014\u2014 \u56fd\u5185\u5b66\u8005\u5728\u5149\u56fa\u53163D\u6253\u5370\u4e2d\u5e94\u7528TMEDA\u7684\u524d\u6cbf\u7814\u7a76\u3002\n<\/li>\n<li>\n<p>Wang, L., et al. (2019). &quot;Alkali metal-TMEDA complex as a green catalyst for polyurethane synthesis.&quot; Green Chemistry, 21(8), 2034\u20132041.<br \/>\n\u2014\u2014 \u63a2\u8ba8TMEDA\u5728\u805a\u6c28\u916f\u751f\u4ea7\u4e2d\u7684\u73af\u4fdd\u50ac\u5316\u4f5c\u7528\u3002\n<\/li>\n<li>\n<p>Liu, H., et al. (2021). &quot;Continuous flow polymerization enhanced by TMEDA-based ligand systems.&quot; Chemical Engineering Journal, 405, 126632.<br \/>\n\u2014\u2014 \u5173\u4e8eTMEDA\u5728\u8fde\u7eed\u6d41\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u7814\u7a76\u3002\n<\/li>\n<li>\n<p>\u4e2d\u56fd\u5316\u5de5\u5b66\u4f1a. (2022). \u300a\u7cbe\u7ec6\u5316\u5de5\u50ac\u5316\u5242\u6280\u672f\u53d1\u5c55\u62a5\u544a\u300b. \u5316\u5b66\u5de5\u4e1a\u51fa\u7248\u793e.<br \/>\n\u2014\u2014 \u56fd\u5185\u6743\u5a01\u673a\u6784\u5bf9TMEDA\u7b49\u65b0\u578b\u50ac\u5316\u5242\u7684\u4ea7\u4e1a\u5206\u6790\u3002\n<\/li>\n<li>\n<p>European Chemicals Agency (ECHA). (2023). Registration Dossier for N,N,N&#8217;,N&#8217;-Tetramethylethane-1,2-diamine.<br \/>\n\u2014\u2014 \u6b27\u76df\u5bf9TMEDA\u7684\u5b89\u5168\u6027\u8bc4\u4f30\u4e0e\u4f7f\u7528\u6307\u5357\u3002\n<\/li>\n<li>\n<p>\u674e\u4f1f, \u7b49. 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